Reactivity of Ir-NSiN Complexes: Ir-Catalyzed Dehydrogenative Silylation of Carboxylic Acids
نویسندگان
چکیده
منابع مشابه
Ru-catalyzed dehydrogenative coupling of carboxylic acids and silanes - a new method for the preparation of silyl ester
Ru(3)(CO)(12)/EtI has been found to be an efficient catalyst system for the dehydrosilylation of carboxylic acids with silanes. In the presence of 1 mol% Ru(3)(CO)(12) and 4 mol% EtI, dehydrosilylation reactions in toluene afforded the corresponding silyl esters at 100 degrees C in good and high yields.
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ژورنال
عنوان ژورنال: ChemCatChem
سال: 2018
ISSN: 1867-3880
DOI: 10.1002/cctc.201701488